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Updated: Jul 17, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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在金属cyclopropene的一个N=N双键的四电子氧化添加

Paul Rathke1, Jonathan Rittle1

  • 1College of Chemistry, University of California Berkeley, Berkeley, CA 94720, USA.

Angewandte Chemie (International ed. in English)
|September 1, 2023
PubMed
概括

这项研究详细介绍了一种新型的基复合物与胺联体,揭示了异常的反应性和 (IV) - 金属cyclopropene结构. 这种复合物经历了一种罕见的4电子氧化添加与阿佐二衍生物,形成一个(VI) diimido复合物.

关键词:
亚二二烯是一种亚二烯.(Chromium) 是一种含的物质.金属cyclopropene的使用情况.氧化添加剂 氧化添加剂斯菲尼尼米德 (Phosphinimides) 是一种的物质.

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