使用多个纳米双胞胎的图灵结构,为演化反应设计高效和稳定的催化剂.
Jialun Gu1,2,3,4, Lanxi Li1,5,4, Youneng Xie1,2,4
1Centre for Advanced Structural Materials, City University of Hong Kong Shenzhen Research Institute, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science, Shenzhen, China.
Nature communications
|September 4, 2023
概括
研究人员开发了一种新的"图灵结构化"方法,以创建用于生产的高度稳定和活性纳米催化剂. 这种创新方法显著提高了用于清洁能源应用的催化剂性能和耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术纳米技术
背景情况:
- 低维纳米晶体是能能量转换的有希望的电催化剂.
- 一个关键的挑战是由于结构退化和应变放松,它们的稳定性有限.
研究的目的:
- 开发一种用于稳定和激活超薄金属纳米板的新策略.
- 为了提高纳米催化剂的效率和耐用性,用于进化反应.
主要方法:
- 利用图灵结构化策略,将高密度纳米双胞胎纳入金属纳米板.
- 通过纳米粒的受约束定向附着实现了稳定的纳米双胞胎网络和应变效应.
- 合成并测试了图灵PtNiNb纳米催化剂.
主要成果:
- 与商业Pt/C相比,图灵PtNiNb纳米催化剂的质量活动增加了23.5倍,稳定性指数增加了3.1倍.
- 使用图灵PtNiNb的离子交换膜水电解仪在1000 mA cm-2下稳定运行超过500小时,金负载较低.
- 图灵结构化策略被证明是有效的,并可扩展到其他基于金属的纳米催化剂 (Ir/Pd/Ag).
结论:
- 图灵结构提供了一种可行的方法来创建内在稳定和高度活跃的纳米催化剂.
- 这种方法显著提升了纳米催化剂在高效能转换和利用方面的潜力.
- 开发的催化剂在水电解中的实际应用方面非常有前途.
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