质子是必要的还是不必要的:对PANI复合材料伪容量储能的新视角
Hongyuan Yu1, Yu Long2, Derong Chen2
1Nanoyang Group, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, National Industry-Education Integration Platform of Energy Storage, Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China.
Small (Weinheim an der Bergstrasse, Germany)
|September 6, 2023
概括
聚氨酸 (PANI) 在性电解质中储存能量而没有质子化,这挑战了以前的假设. 这一发现为基于PANI的储能材料开辟了新的途径.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 聚氨酸 (PANI) 储能传统上依赖于质子化进行伪电容.
- 在没有质子化的性电解质中,PANI的伪电容能力在很大程度上仍未被探索.
研究的目的:
- 为了证明在没有质子化的PANI中伪容量储能.
- 研究性介质中的PANI电荷储存机制.
- 为了评估基于PANI的复合材料在性电解质中的性能.
主要方法:
- 制造PANI/石墨烯复合物作为一个模型系统.
- 在现场拉曼光谱分析PANI链的变化.
- 电化学石英晶体微平衡 (EQCM) 用于监测反应期间的质量变化.
主要成果:
- 在没有质子化的性电解质中证明了PANI的伪电容储能.
- 确定了-N=组的形成以及OH-在氧化反应中的作用.
- 与酸性电解质相比,实现了卓越的循环稳定性和更广泛的操作电压 (1V).
结论:
- PANI表现出独立于质子化的伪容量储能能力.
- 氧化离子直接参与非质子化氧化机制.
- PANI/石墨烯复合材料在性电解质中显示出有希望的性能,用于储能应用.
相关概念视频
Energy Stored in Capacitors
526
A parallel plate capacitor, when connected to a battery, develops a potential difference across its plates. This potential difference is key to the operation of the capacitor, as it determines how much electrical energy the capacitor can store.
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
526
Energy Stored in a Capacitor
3.7K
When an archer pulls the string in a bow, he saves the work done in the form of elastic potential energy. When he releases the string, the potential energy is released as kinetic energy of the arrow. A capacitor works on the same principle in which the work done is saved as electric potential energy. The potential energy (UC) could be calculated by measuring the work done (W) to charge the capacitor.
3.7K
Dielectric Polarization in a Capacitor
4.8K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
4.8K
Energy Stored in a Capacitor: Problem Solving
1.1K
In 1749, Benjamin Franklin coined the word battery for a series of capacitors connected to store energy. Capacitors store electric potential energy that can be released over a short time. This property means capacitors have a wide range of applications.
Capacitor-discharge ignition is a type of ignition system commonly found in small engines where the energy released from a capacitor ignites an induction coil that, in turn, fires the spark plug.
To calculate the energy stored in a capacitor of...
Capacitor-discharge ignition is a type of ignition system commonly found in small engines where the energy released from a capacitor ignites an induction coil that, in turn, fires the spark plug.
To calculate the energy stored in a capacitor of...
1.1K
Capacitor With A Dielectric
4.0K
Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
4.0K
MOS Capacitor
833
A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
833


