在缩的电解质中进行低选:在聚电解质刷中重新进入的胀
Hayden Robertson1, Gareth R Elliott1, Andrew R J Nelson2
1College of Science, Engineering and Environment, University of Newcastle, Callaghan, NSW 2308, Australia. willott.joshua@gmail.com.
Physical chemistry chemical physics : PCCP
|September 6, 2023
概括
高度的盐会导致意外的多电解质刷胀,称为底. 这种现象挑战了经典的电解质理论,揭示了高离子强度的局限性.
科学领域:
- 聚合物科学 聚合物科学
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
背景情况:
- 超的环境和技术过程涉及高度的盐.
- 经验研究表明,在高盐度下预测和观察到的查长度之间存在差异,称为低查.
- 经典的电解质理论努力解释极端盐度的现象.
研究的目的:
- 为了研究下面屏幕的现象,使用阴离子聚电解质刷.
- 分析不同度的聚合物刷的结构变化和膨胀反应.
- 将实验结果与理论预测进行比较.
主要方法:
- 聚电解质刷的合成方法:聚二甲基氧乙三甲基 (PMETAC).
- 中子反射测量和光谱圆测量用于监测内部结构和胀.
- 在一系列单价和多价电解质度的实验测量.
主要成果:
- 随着单价电解质度的增加,PMETAC刷的单调崩.
- 在高度的多价电解质中,PMETAC刷子的非单调的回流胀,表明底.
- 数字自相一致的场理论预测与低至中等盐度的实验一致.
结论:
- 经典的电解质理论不足以描述在高盐度下选的长度.
- 在聚电解质刷中重新进入的胀与底部选现象一致.
- 这项研究强调了需要精细的理论来解释高盐条件下的聚合物行为.
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