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Updated: Jul 17, 2025

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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Published on: June 9, 2023

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多硫化物的稳定性和半导体行为由无等价的sp3混合化

Guang Zhang1, Kai Wang1, Qiaoyu Liu2,3

  • 1College of Material Science and Engineering, Liaoning Technical University, Fuxin 123000, China.

Inorganic chemistry
|September 6, 2023
PubMed
概括

硫电池看起来很有前途,但中间聚硫化物不太了解. 这项研究揭示了稳定和转移稳定的聚硫化物,澄清了它们的结构和电子特性,以提高电池性能.

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相关概念视频

Hybridization of Atomic Orbitals I03:24

Hybridization of Atomic Orbitals I

The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
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The contact of metal and semiconductor can lead to the formation of a junction with either Schottky or Ohmic behavior.
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Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The...
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