在纳米尺寸的薄液体片中分离压力效应和蒸发延长半月板的间距模型
1School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Langmuir : the ACS journal of surfaces and colloids
|September 7, 2023
概括
一个新的中镜模型准确地描述了纳米尺度薄液体薄膜中的分离压力效应,这对于理解纳米孔中的蒸发和液体运输至关重要. 该模型自行调整薄膜厚度和接触角度与蒸发速度.
科学领域:
- 物理 物理学 物理
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
背景情况:
- 分离压力对于接触线动力学,微/纳米尺度相变热传输和纳米孔中的液体运输至关重要.
- 现有的模型往往难以完全捕捉纳米尺寸薄液体薄膜中力量的复杂相互作用.
研究的目的:
- 开发和验证一个介光学模型,用于在纳米尺度薄液体薄膜中解离压力效应.
- 通过使用开发的模型,研究纳米通道中蒸发阴道的特性.
主要方法:
- 结合了纳米级液体-蒸汽界面传输的美索斯科普方法.
- 对于长距离的固体-流体分子相互作用,利用了平均场近似.
- 根据分子动力学模拟和运动理论验证了模型.
主要成果:
- 该模型准确地预测了哈迈克尔常数和短暂的蒸发/凝结质量流量.
- 成功捕获了不同的区域:不蒸发的薄膜,蒸发的薄膜和内在的半径.
- 证明了表面接触角度和薄膜厚度与蒸发速度的自调.
结论:
- 分离压力主导非蒸发区域,抑制蒸发.
- 毛细管的压力控制着内在半月的区域.
- 这两种压力都推动液体运输到蒸发的薄膜区域,补偿质量损失.
相关概念视频
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
340
Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the...
340
The Fluid Mosaic Model
148.8K
The fluid mosaic model was first proposed as a visual representation of research observations. The model comprises the composition and dynamics of membranes and serves as a foundation for future membrane-related studies. The model depicts the structure of the plasma membrane with a variety of components, which include phospholipids, proteins, and carbohydrates. These integral molecules are loosely bound, defining the cell’s border and providing fluidity for optimal function.
148.8K
Surface Tension of Fluid
329
Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies...
Surface tension varies...
329
Excess Pressure Inside a Drop and a Bubble
1.7K
The shape of a small drop of liquid can be considered spherical, neglecting the effect of gravity. This drop can further be considered as two equal hemispherical drops put together due to surface tension. The forces acting on the spherical drop are due to the pressure of the liquid inside the drop, the pressure due to air outside the drop, and the force due to the surface tension acting on the two hemispherical drops.
1.7K
Surface Tension, Capillary Action, and Viscosity
28.0K
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
28.0K
Concept of Pressure at a Point
287
The concept of pressure at a point in a fluid establishes that pressure within a fluid is uniform in all directions at a specific location. This uniformity occurs because fluid molecules exert force evenly across any point due to their random motion and continuous collisions within the fluid. Pressure at a point is determined by the surrounding fluid molecules and is influenced by factors like depth and density, rather than by shape or orientation.
In a fluid at rest, pressure acts equally in...
In a fluid at rest, pressure acts equally in...
287


