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Updated: Jul 17, 2025

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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通过单个氨基分子作为载体在p-aminobenzoic酸中的高效的分子内质子转移

Keijiro Ohshimo1, Ryosuke Sato1, Yuya Takasaki1

  • 1Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.

The journal of physical chemistry letters
|September 7, 2023
PubMed
概括

这项研究表明,单个氨基分子可以作为一种载体,在质子化p-aminobenzoic酸 (PABA·H+) 中有效转移质子. 这为气相质子转移中很少报道的载体机制提供了新的见解.

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Amines can behave as Brønsted–Lowry bases by accepting a proton from the acid to form corresponding conjugate acids. Due to a lone pair of nonbonding electrons, aliphatic amines can also act as Lewis bases by forming a covalent bond with an electrophile.
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