铜尾矿的浸出行为使用hydantoin环氧树脂和红色粘土固化/稳定
Kaofei Zhu1, Yong He1, Deshan Feng1
1Key Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Monitoring (Central South University), Ministry of Education, Changsha 410083, PR China; School of Geosciences and Info-Physics, Central South University, Changsha 410083, PR China.
Journal of environmental management
|September 7, 2023
概括
这项研究引入了一种新方法,使用水素环氧树脂 (HER) 和红色粘土来稳定铜尾矿,有效减少铜出并提高环境安全.
科学领域:
- 环境工程 环境工程
- 地质技术工程 地质技术工程
- 材料科学 材料科学 材料科学
背景情况:
- 采矿和炼尾矿带来了重大的环境和健康风险.
- 现有的废弃物处理方法在环境兼容性,稳定性和成本效益方面存在局限性.
研究的目的:
- 开发和评估一种新型的固化/稳定技术,用于铜尾矿使用氧树脂 (HER) 和红色粘土.
- 在各种条件下,包括酸雨,研究经过处理的铜尾矿的浸出行为,透性和微观结构变化.
主要方法:
- 毒性特征漏程序 (TCLP) 测试用于分析漏特征.
- 灵活墙柱测试,以评估在模拟酸雨下透性和浸出性.
- 微观结构测试以检查固化尾矿的变化.
主要成果:
- HER和红色粘土固化/稳定技术证明了铜尾矿的良好毒性稳定.
- 在TCLP和柱体试验中,铜漏度仍然低于中国国家标准.
- 红色粘土含量增加显著减少了铜出.
- 酸雨改变了矿物成分和微观结构,增加了多孔性,但更高的pH值导致液压导电率略有下降.
结论:
- 开发的技术有效地固定了废弃物中的铜,符合环境标准.
- 红色粘土含量是提高稳定性能的关键因素.
- 酸雨影响固化尾矿的长期稳定性和透性,在5%的红粘土含量下观察到最佳性能.
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