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相关概念视频

Precipitation of Ions03:11

Precipitation of Ions

28.0K
Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
28.0K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.7K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.7K
Electrolysis03:00

Electrolysis

26.6K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.6K
Electrophilic Aromatic Substitution: Fluorination and Iodination of Benzene01:13

Electrophilic Aromatic Substitution: Fluorination and Iodination of Benzene

6.1K
Bromination and chlorination of aromatic rings by electrophilic aromatic substitution reactions are easily achieved, but fluorination and iodination are difficult to achieve. Fluorine is so reactive that its reaction with benzene is difficult to control, resulting in poor yields of monofluoroaromatic products. To address this, Selectfluor reagent is used as a fluorine source in which a fluorine atom is bonded to a positively charged nitrogen.
6.1K
Formation of Complex Ions03:45

Formation of Complex Ions

23.7K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.7K
Redox Titration: Iodimetry and Iodometry01:23

Redox Titration: Iodimetry and Iodometry

1.9K
Iodometry and iodimetry are analytical methods used to determine the concentration of oxidizing or reducing agents using iodine. In iodometric titrations, the oxidizing analyte solution is usually acidified and treated with an excess of iodide ions, which generates an equivalent amount of iodine in equilibrium with triiodide. The released iodine is subsequently titrated directly against a standardized reducing agent. As the dilute iodine color becomes pale yellow, a few drops of freshly...
1.9K

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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

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一个由水溶液中间化学作用启动的十二电子转换阴极.

Wenjiao Ma1, Tingting Liu1, Chen Xu1

  • 1State Key Laboratory of Chem/Bio-Sensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China.

Nature communications
|September 7, 2023
PubMed
概括

研究人员开发了一种新的12电子转移电极,用于高能量密度的水性电池. 这一突破利用了间素化学,实现了电子转移的六倍增长,提高了电池的性能.

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科学领域:

  • 电化学 电化学 电化学
  • 材料科学 材料科学 材料科学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 高能量密度电池需要具有多电子转移能力和高氧化还原潜力的氧化还原对.
  • 传统的水性电池往往面临能量密度的限制,因为有氧还原对的约束.

研究的目的:

  • 开发一种新的12电子转移电极,用于先进的水性电池.
  • 提高水性电池系统的能量密度和电化学性能.

主要方法:

  • 研究了一种基于水性电解质中化/酸转换的十二电子转移电极.
  • 在酸性电解质中利用和之间的间化学反应来创建电化学-化学循环 (-酸循环).
  • 在一个-全电池和一个酸脱电池中评估了电极的性能.

主要成果:

  • 实现了12个电子的转移,比传统的/配对大6倍.
  • 展示了1200 mAh的高特异性容量,具有良好的可逆性.
  • 报告了开发的电极的1357Wh kg-1的高能量密度.

结论:

  • 新的12电子电极显示了未来高能量密度水性电池设计的重大前景.
  • 间素介导的电化学-化学循环有效地加快了反应动力学和可逆性.
  • 在实际电池配置中验证了该系统的潜力,例如-和酸脱电池.