用兰化物添加的KMgF3升级转换纳米粒子用于光子雪崩发光,具有巨大的非线性
Meiran Zhang1,2,3, Ping Huang1,2,3, Wei Zheng1,2,3
1CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, and State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Nano letters
|September 8, 2023
概括
研究人员使用一种新溶解方法开发了新的合兰化物升级转化纳米粒子. 这一策略通过防止火来增强光子雪崩发光,为先进的光学技术铺平了道路.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 光子学 是一个光子学.
背景情况:
- 添加兰化物 (Ln3+) 的升级转化纳米粒子 (UCNPs) 显示出先进技术的前景.
- 在UCNP中,高效的光子雪崩 (PA) 发光受到表面和格子灭效应的阻碍.
研究的目的:
- 开发一种可控合成方法,用于异构的Ln3+-doped KMgF3UCNPs.
- 为了减轻UCNP中的发光灭,并提高PA的效率.
主要方法:
- 使用KHF2的热解来控制KMgF3UCNP的合成.
- 纳入有价的Ln3+兴奋剂,以防止OH-缺陷.
主要成果:
- 从802nm的Tm3+在KMgF3:Tm3+UCNPs中实现了高效的PA发光.
- 显示了高的非线性 (∼27),PA响应时间为281毫秒,以及低的激发值 (16.6 kW cm-2).
结论:
- 在KHF2热解方法有效地抑制了UCNP中的发光灭.
- 异性Ln3+兴奋剂和晶格工程为高度非线性PA发光提供了一条新路线.
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