共价有机框架功能化智能膜,具有低液体双重超性,用于有效分离油/水乳液
Yaqi Zhang1, Shiwei Tian1, Qiankun Sha2
1State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin 300387, China; Tianjin Municipal Key Laboratory of Advanced Fiber and Energy Storage Technology, School of Materials Science and Engineering, Tiangong University, Tianjin 300387, China.
The Science of the total environment
|September 8, 2023
概括
研究人员开发了一种具有双重超级性智能膜,用于高效的油/水乳液分离. 这种COF功能化的膜为油性废水处理提供高流量,卓越的效率和可重复使用性.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 纳米技术纳米技术
背景情况:
- 油/水乳液在废水处理中带来了重大挑战.
- 能够按需分离的智能膜对于复杂的工业应用至关重要.
研究的目的:
- 制造一种具有低液体双重超级化能力的智能膜,以有效地分离油/水乳液.
- 为了研究开发的膜的分离性能,可重复使用性和防腐性质.
主要方法:
- 制造的 imine-链接的共价有机框架 (TPB-DMTP-COF) 的纳米球.
- 以TPB-DMTP-COF纳米球为基础的多烯基基 (PAN) 膜的功能化.
- 通过预湿过程,评估膜在分离油中的水和油中的水乳液中的性能.
主要成果:
- 在液体下,TPB-DMTP-COF/PAN膜表现出双重超性 (接触角大于150°).
- 在两种类型的乳液中都实现了高分离流量 (高达2100 L/m2·h) 和效率 (>97.4%).
- 这些膜表现出了出色的可重复使用性和抗抗性,这是由于液体粘附度超低.
结论:
- 建立了一种可行的方法来创建具有低液体双重超性智能膜.
- 开发的TPB-DMTP-COF/PAN膜显示了油性废水处理应用的巨大潜力.
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