用SThM技术量化测量热导电性:测量,校准协议和不确定性评估
Nolwenn Fleurence1, Séverine Demeyer1, Alexandre Allard2
1Laboratoire National de Métrologie et d'Essais (LNE), 29, Avenue Roger Hennequin, 78197 Trappes, France.
Nanomaterials (Basel, Switzerland)
|September 9, 2023
概括
扫描热显微镜 (SThM) 能够在纳米尺度上进行定量导热量测量. 这种技术对低导热率材料 (k<10 Wm-1K-1) 有效,不确定性为10%.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 热物理 热物理
背景情况:
- 有效的热管理对于缩小电子元件至关重要.
- 薄膜和纳米线等纳米结构材料越来越多地用于电子产品.
- 在纳米尺度上描述热性质需要专门的技术.
研究的目的:
- 开发和验证使用扫描热显微镜 (SThM) 进行定量导热量测量的测量和校准协议.
- 评估与纳米结构材料的SThM测量相关的不确定性.
主要方法:
- 使用了主动模式扫描热显微镜 (SThM) 带有热电阻探针.
- 开发了使用已知宏观导热率的样品的校准协议.
- 建立了一个校准曲线,将探头阻力变化与导热率联系起来.
- 进行了对校准和测量的全面不确定性评估.
主要成果:
- 在相同的传热条件下 (扩散热状态) 实现了量化和可追溯的导热度测量.
- 使用参考材料建立了校准曲线.
- 对于SThM测量,获得了10%的不确定性.
- 该研究发现了对具有低导热率 (k<10 Wm-1K-1) 的材料进行定量SThM测量的局限性.
结论:
- SThM是一种用于定量纳米级导热量测量的可行技术.
- 准确的测量需要仔细校准和相同的热状态.
- 该技术的适用性目前仅限于低导热性的材料.
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