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发光 5,6 个成员双 (金属环) (II) 复合物的合成和生物活性

Jing Jing¹, Miao Yu¹, Lei Pan¹

¹Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province, College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China.

Molecules (Basel, Switzerland)

|September 9, 2023

概括

具有独特结构的新 (II) 复合体表现出发光. 干体的设计显著影响它们的排放特性和细胞成像和细胞毒性应用的潜力.

科学领域:

有机金属化学有机金属化学
协调化学协调化学
材料科学材料科学材料科学

背景情况:

(II) 复合物因其独特的光物理性质而受到研究.
金属自行车提供可调节的电子和结构特性.
发光 ((II) 复合物在传感和成像方面具有潜在的应用.

研究的目的:

合成和表征新型的5,6个组成的双 (金属环) (II) 复合物.
研究辅助配体 (乙化物,异化物) 和循环金属化配体 (N^N'*C,N^C*N') 对光物理性质的影响.
评估这些发光复合体的细胞毒性和细胞成像能力.

主要方法:

四对 (II) 复合物的合成和表征.
单晶X射线衍射用于结构确定.
光发光谱学用于在室温下研究辐射特性.
细胞毒性测定和细胞成像研究.

主要成果:

所有合成的复合物在室温下在溶液和固体状态都具有发射性.
与异化物协调的复合物相比,乙化物协调的复合物具有较低的能量排放.
循环金属化联体结构 (N^N'*C与N^C*N') 对排放的影响比辅助联体更为明显.
复合体表现出不同程度的细胞毒性和细胞成像潜力.

结论:

(II) 双 (metallacyclic) 复合物的排放特性是通过连接体设计高度调节的.
循环金属化联体结构在决定排放特征方面发挥着关键作用.
这些复合物对生物医学成像和基治疗的应用具有前景.

关键词:

5,6个成员的二氧化 (金属循环)生物活动是生物活动.晶体结构的结晶结构.排放量排放量排放量排放量排放量排放量 () 复合物 (二) 复合物 (二) 复合物 (三) 复合物 (四) 复合物

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