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在易碎的乙烯基乙树脂中的工程性,使用尿烯酸用于增材制造
Mohanad Idrees1, Heedong Yoon1, Giuseppe R Palmese1
1Department of Chemical and Biological Engineering, Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104, USA.
Polymers
|September 9, 2023
概括
将尿烯酸盐添加到易碎树脂中可以提高性. 最佳度增强机械性能,在热固化聚合物中显示了刚性和性之间的平衡.
科学领域:
- 聚合物科学 聚合物科学
- 材料工程 材料工程 材料工程
- 添加剂制造 添加剂制造 添加剂制造
背景情况:
- 热性聚合物表现出与交叉连接密度相关的刚性-性权衡.
- 工程聚合物网络,如尿寡合物,可能会提高性.
- 甲化Bis-GMA (DA2) 是一种易碎的树脂,通常用于3D打印.
研究的目的:
- 为了研究商用尿烯酸树脂 (Tenacious) 对脆性甲基化 Bis-GMA (DA2) 树脂的增硬效应.
- 为了确定最佳的混合比例,以提高性和机械性能.
- 探索聚合物混合物中的模量和强度的协同效应.
主要方法:
- DA2和Tenacious的配方以不同的重量百分比准备.
- 零件使用光聚合,一种3D打印技术来制造.
- 评估了印刷材料的机械,热和断裂性能.
主要成果:
- 在Tenacious.的约60%重量/重量下,可以实现显著的硬化.
- 机械性质,包括模量和强度,当性含量超过60%w/w时就会下降.
- 观察到协同效应,在特定的混合度下增强模量和强度.
结论:
- 在热树脂中优化尿烯酸盐含量可以提高性,而不会显著损失机械完整性.
- 瓦特光聚合是一种生产硬化聚合物混合物的可行方法.
- 该研究强调了定制聚合物网络设计的潜力,以克服固有的材料限制.
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