制备和分散性能 疏水性吸烟水性分散
Jinglu Xu1, Jihu Wang1, Shaoguo Wen1
1College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China.
Polymers
|September 9, 2023
概括
用非离子聚合物分散剂优化了水性涂料中疏水性烟氧化 (HFS) 的分散. 优化的条件产生了稳定的HFS水性分散物,其颗粒大小得到了改善,这对于质修饰至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 合体和表面化学
背景情况:
- 疏水性烟二氧化 (HFS) 是水性涂料中的一个关键的类风学添加剂.
- 有效分散HFS对于实现所需的涂层性能至关重要.
研究的目的:
- 在水系统中研究和优化疏水性烟二氧化 (HFS) 的分散技术.
- 评估分散条件和分散剂对HFS粒子大小和稳定性的影响.
主要方法:
- 传输电子显微镜 (TEM) 用于初级粒子大小分析 (D50 = 13.6 nm,D90 = 19.7 nm).
- 动态光散射 (DLS) 用于粒子大小和散射性能评估.
- 用水源多烯酸乳和聚氨树脂制备HFS水性分散和复合.
- 能量分散光谱 (EDS) 用于涂料中的元素分布分析.
主要成果:
- 非离子聚合物分散剂表现出最好的HFS分散性能.
- 优化的分散条件导致HFS水性分散颗粒大小为D50 = 27.2 nm.
- 准备的HFS水性分散物表现出优异的储存稳定性,在47天后没有显著的颗粒大小变化.
结论:
- 使用非离子聚合物分散剂的优化分散技术显著改善了水载系统中的HFS分散.
- 开发的HFS水性分散是稳定的,适合用于水性涂料.
- 这项研究为提高HFS作为rheology添加剂的性能提供了基础.
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