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在漂浮过程中Lignosulfonates的发泡特性
Jhon Chique1, Lina Uribe2,3, Marek Pawlik4
1Department of Metallurgical Engineering, University of Concepcion, Concepción 4040371, Chile.
Polymers
|September 9, 2023
概括
硫酸盐提供了一个环保的替代品硫化 (NaSH) 浮化. 这些化合物表现出表面活性,并影响泡性,泡大小和水回收,影响漂浮效率.
科学领域:
- 矿物加工和提取性金 矿物加工和提取性金
- 表面化学和合体科学
背景情况:
- 使用硫化 (NaSH) 进行传统的铜和化浮动,由于有毒的H2S气体排放和气味,造成环境风险.
- 利格诺硫酸盐已经显示出抑制卜丁的潜力,但它们对漂浮泡特性的影响仍未得到充分研究.
研究的目的:
- 在矿物浮动的背景下,研究三种不同的线硫酸盐样本 (NaLS,CaLS,KLS) 的发泡特性.
- 评估硫酸盐对表面张力,泡性,泡大小分布和水回收的影响.
主要方法:
- 在不同的pH水平上进行了表面张力测量.
- 使用动态发泡能力指数 (DFI) 评估了发泡能力.
- 气泡大小分布和水回收通过在双相系统中的漂浮实验来确定.
主要成果:
- 所有测试的硫酸盐都表现出表面活性,其表面活性随着pH值的增加而降低,并与度和分子量相关.
- 与硫酸盐 (CaLS) 和 kraft 硫酸盐 (KLS) 相比,硫酸盐 (NaLS) 的动态发泡度指数 (DFI) 是最高的.
- 硫酸盐显著影响了泡大小,其中KLS和NaLS对水回收产生了最强烈的影响,与表面张力和泡性发现一致.
结论:
- 硫酸盐具有与矿物浮动过程相关的固有表面活性和泡修饰能力.
- 经过测试的酸硫酸盐,特别是NaLS和KLS,在漂浮中表现出有前途的泡或修饰剂,可能为NASH提供更环保的替代品.
- 对优化硫酸盐结构和应用的进一步研究是有必要的,以增强卜丁酸盐和硫化铜漂浮.
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