在石中NMR自我扩散和横向放松时间:衰老的影响
Michele Porto1,2, Ruggero Angelico3, Pietro Calandra4,2
1Department of Chemistry and Chemical Technologies, University of Calabria, Via P. Bucci, Cubo 14/D, Rende, CS, 87036, Italy.
Chemphyschem : a European journal of chemical physics and physical chemistry
|September 10, 2023
概括
老龄化增加了青的数量.
科学领域:
- 材料科学与工程 材料科学与工程
- 物理化学 物理化学
背景情况:
- 矿的老化会改变其质和分子性质.
- 了解分子动力学对于预测矿性能至关重要.
研究的目的:
- 在各种老化条件下研究两种青类型的分子动力学.
- 为了将衰老效应与自我扩散和放松时间的变化相关联.
主要方法:
- 动态剪切风湿测量 (DSR) 对于风湿学性质.
- 核磁共振 (NMR) 技术包括脉冲场梯度刺激回声 (PFGSE) 和放松计 (CPMG).
- 人工衰老协议 (短期和长期).
主要成果:
- 凝溶液过渡温度随着老化时间的增加而增加.
- 石粘度Arrhenius参数与简单液体的参数之间的意想不到的相关性.
- 观察并描述了自我扩散系数 (D) 的广泛分布和横向放松时间 (T2) 的连续单模分布.
结论:
- 衰老显著影响青的分子动力学.
- 矿系统与简单的液体共享着基本的分子过程.
- 核磁共振 (NMR) 提供了关于青的衰老机制的宝贵见解.
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