操作条件和溶液化学对奥斯莫斯膜结构和性能的影响
Mavis C Y Wong1, Kristina Martinez1, Guy Z Ramon1
1Department of Civil and Environmental Engineering and California NanoSystems Institute, University of California, Los Angeles, California, USA.
概括
纤维素三酸盐 (CTA) 膜性能对温度和溶液化学反应敏感. 操作模式 (PRO模式与FO模式) 在不同的条件下显著影响CTA膜的稳定性和性能.
科学领域:
- 膜科学和技术 膜科学和技术
- 材料科学是一种材料科学.
- 化学工程是化学工程的组成部分.
背景情况:
- 纤维素三酸盐 (CTA) 膜用于各种分离工艺.
- 了解不同操作条件下的性能变化对于优化应用程序至关重要.
研究的目的:
- 系统地评估工作条件和溶液化学如何影响CTA膜性能.
- 提供关于CTA膜在特定应用中的优缺点的见解.
主要方法:
- 研究了水和盐透性的变化,以及CTA膜的膜结构参数.
- 多样化的操作条件,包括料和吸水溶液的流量和温度.
- 检查了吸取溶液离子强度和离子存在的影响.
主要成果:
- 在PRO模式下,流速变化对CTA膜性能的影响很小.
- 温度升高和吸取溶液的离子强度改变了膜的透性和结构.
- 双价阳离子加剧了胀效应,影响了性能.
- 与FO模式相比,CTA膜结构参数在PRO模式下对外部因素的敏感性较低.
结论:
- CTA膜的性能受到温度和吸水溶液化学的显著影响.
- 操作模式 (PRO与FO) 决定了膜对外部因素的敏感性.
- 这些发现为定制CTA膜在分离技术中的使用提供了宝贵的见解.
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