基于烯的发光材料的聚合行为,从分子设计和光学特性到应用
Xing Feng1, Xiaohui Wang1, Carl Redshaw2
1Guangdong Provincial Key Laboratory of Information Photonics Technology, School of Material and Energy, Guangdong University of Technology, Guangzhou, 510006, P. R. China. hyxhn@sina.com.
Chemical Society reviews
|September 11, 2023
概括
分子聚合物,特别是以烯为基础的材料,表现出独特的发光特性,受其结构和聚合状态的影响. 本综述探讨了聚合行为如何增强高级应用的光电子特性.
科学领域:
- 材料科学 材料科学 材料科学
- 超分子化学 超分子化学
- 有机电子 有机电子
背景情况:
- 分子聚合物通过弱相互作用自我组装,从而产生新兴性质.
- 典型的光体Pyrene表现出不同的发光,取决于聚合状态,分子包装和形态.
- 聚合诱导排放 (AIE) 刺激了对基材料的研究,但聚合行为本身尚未得到充分探索.
研究的目的:
- 通过聚合增强的基于烯的发光材料的光电子特性进行审查.
- 系统地建立结构-属性关系,考虑分子结构和聚合状态.
- 为基于烯的材料的发光和电子过渡机制提供一个新的视角.
主要方法:
- 文献综述,重点关注以烯为基础的发光材料及其聚合行为.
- 在聚合式烯系统中分析结构属性关系.
- 新型烯衍生物的合成和表征 (从抽象中暗示).
主要成果:
- 聚合显著改变了烯的发光,往往导致红移发射和改变量子产量.
- 基于烯的新型发射器具有独特的特性,如循环极化发光,增强的光/光和电光发光.
- 聚合烯材料在化学传感器,OLED,OFET,太阳能电池和电池方面显示出潜力.
结论:
- 聚合状态和分子包装对于烯基材料的光电子特性至关重要.
- 了解聚合行为是解锁烯化学的先进应用的关键.
- 这篇综述提供了对发光机制的洞察,并促进了以烯为基础的功能材料的未来发展.
相关概念视频
Photoluminescence: Applications
428
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
428
Photoluminescence: Fluorescence and Phosphorescence
2.1K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
2.1K
Variables Affecting Phosphorescence and Fluorescence
526
Fluorescence and phosphorescence are essential phenomena in fields like analytical chemistry, biological imaging, and materials science, where they detect molecular properties and visualize cellular structures. Understanding the variables that influence these luminescent behaviors is crucial for maximizing accuracy and efficiency in their applications. These variables can broadly be grouped into chemical structure, solvent properties, and external conditions, each playing a distinct role in...
526


