[化学氧气需求 (COD) 构成和贡献在白阳地湖的典型水域]
Qi Li1,2, Chao Zhang1, Wen-Qiang Zhang1
1State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.
Huan jing ke xue= Huanjing kexue
|September 12, 2023
概括
白阳地湖的化学氧需求 (COD) 主要来自溶解的有机物,而不是无机物质. 二色酸盐方法可能会高估因耐火溶解有机物 (RDOC) 的污染.
科学领域:
- 环境化学环境化学
- 评估水质水质的评估.
- 有机地化学 有机地化学
背景情况:
- 化学氧气需求 (COD) 是评估水体有机污染的一个关键指标.
- 了解消耗氧气的有机物质的组成和来源对于准确的污染评估至关重要.
研究的目的:
- 调查 Baiyangdian湖中消耗氧气的有机物质的组成,来源和影响因素.
- 分析不同有机物成分对COD的贡献.
- 评估二酸盐方法在这种特定环境中用于COD测量的准确性.
主要方法:
- 物理连续分类的物理连续分类.
- 三维光光谱学 三维光光谱学
- 分析总有机碳 (TOC) 释放流量.
- 光指数和生物指数测量
主要成果:
- 溶解的有机物质 (<220nm),特别是类似蛋白质和类似湿土的物质,占COD的59%-93%.
- 上层水中的有机物源于植被分解,沉积物释放和陆地/人工污染.
- 沉积物有机物主要受到陆地源的影响.
- 耐火溶解有机物 (RDOC) 被确定为白阳地湖COD的主要驱动因素.
结论:
- 无机物质对COD水平的影响最小.
- 白阳地湖的COD受到内源和外源有机物来源的显著影响.
- 二酸盐方法可能会高估有机污染,原因是RDOC的快速氧化,在自然条件下慢慢降解.
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