双相环氧化生物陶的组成,加工和特性:与竞争强度和光学特性之间的关系
Chek Hai Lim1, Sonaj Vardhaman1, Niyati Reddy1
1Department of Preventive and Restorative Sciences, School of Dental Medicine, University of Pennsylvania, PA 19104, USA.
概括
用于牙科修复的伊特里亚稳定 (YSZ) 生物陶显示出强度和半透明度的权衡. 优化处理可能会同时增强两个属性,挑战当前的理解.
科学领域:
- 生物材料科学 生物材料科学
- 材料科学 材料科学 材料科学
- 陶工程 陶工程
背景情况:
- 双相陶生物陶,特别是伊特里亚稳定陶 (YSZ),对于现代牙科修复至关重要.
- 了解组成,处理,结构和属性之间的相互作用是优化YSZ性能的关键.
研究的目的:
- 研究3-5mol%YSZ生物陶的组成,加工,结构和特性之间的关系.
- 分析烧结条件,立方和四角含量以及颗粒大小如何影响YSZ强度和半透明度.
- 探索优化YSZ临床材料属性的潜在加工路径.
主要方法:
- 3YSZ,4YSZ和5YSZ的结晶形状,密度和微观结构的表征.
- 通过严格的测试来评估强度和光学性能.
- 对烧结温度,立方相含量和粒度大小的依赖性的分析.
主要成果:
- YSZ强度与具有显著格子扭曲的四角 (t-ZrO2) 的数量相关.
- 透光性与立方 (c-ZrO2) 和较少扭曲的四角有关.
- 虽然强度通常为3YSZ>4YSZ>5YSZ,半透明度则相反,但强度可以随着半透明度的增加而增加,在最佳的烧结3YSZ和4YSZ中.
结论:
- 该研究揭示了YSZ组成,加工和特性之间的细微关系,特别是关于强度和半透明度.
- 观察到的趋势表明,优化烧结可以提高强度和半透明度,这与一些普遍的假设相反.
- 这些发现为开发用于牙科应用的先进土生物陶提供了新的加工策略.
相关概念视频
Properties of Transition Metals
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
Stereoisomerism
Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
Properties of Enantiomers and Optical Activity
It is essential to understand the difference between chiral and achiral interactions and the implications thereof in optical activity and their applications. Just as our feet, which are chiral, interact uniquely with chiral objects, such as a pair of shoes, but identically with achiral socks, enantiomers of a molecule exhibit different properties only when they interact with other chiral media. An example of a significant implication from this facet is the phenomenon known as optical activity,...
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
Sharpless Epoxidation
The conversion of allylic alcohols into epoxides using the chiral catalyst was discovered by K. Barry Sharpless and is known as Sharpless epoxidation. The use of a chiral catalyst enables the formation of one enantiomer of the product in excess. This chiral catalyst is mainly a chiral complex of titanium tetraisopropoxide and tartrate ester (specific stereoisomer). The stereoisomer used in the chiral catalyst dictates the formation of the enantiomer of the product. In other words, the use of...
Diels–Alder Reaction Forming Cyclic Products: Stereochemistry
The Diels–Alder reaction is one of the robust methods for synthesizing unsaturated six-membered rings. The reaction involves a concerted cyclic movement of six π electrons: four π electrons from the diene and two π electrons from the dienophile.


