Pd- (±) - (±) - B

Yota Uwabe1, Kei Muto2, Junichiro Yamaguchi1

  • 1Department of Applied Chemistry, Waseda University, 513 Wasedatsurumakicho, Shinjuku, Tokyo, 162-0041, Japan.

概括

实现了C11氧化的Cephalotaxus类化合物,财富环素A和B以及头素B的总合成. 关键的方法包括Pd催化 dearomative 螺旋循环和酸介导的合转化.

相关概念视频

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