非对称的 Π-桥工程使高允许性[1,2-B:4,5-b'] furan结合聚合物成为高效的有机太阳能电池
Yueyue Gao1, Zuo Xiao2, Minghuan Cui3
1Key Laboratory of Photovoltaic Materials, School of Future Technology, Henan University, Kaifeng, 475004, P. R. China.
Advanced materials (Deerfield Beach, Fla.)
|September 13, 2023
概括
研究人员开发了用于有机太阳能电池 (OSC) 的新型联共聚物. PBDF-TF-BTz聚合物供体表现出高介电常数,从而提高了设备的性能和18.10%的功率转换效率.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 太阳能光伏发电是如何实现的
背景情况:
- 有机太阳能电池 (OSC) 依赖于由材料介电常数影响的电荷动态.
- 开发新的联共聚物对于提高OSC性能至关重要.
研究的目的:
- 设计和合成基于[1,2-b:4,5-b']二 (BDF) 和 (BTz) 的新型联共聚物.
- 研究π桥结构对介电常数和分子包装的影响.
- 使用这些新型材料优化OSC性能.
主要方法:
- 合成具有不同π桥的BDF-BTz合共聚物.
- 介电常数 (ɛr) 的表征,分子包装和可混合性.
- 使用非富勒烯接受器Y6和富勒烯衍生物PCBO-12的OSC装置的制造和测试.
主要成果:
- 与同行相比,PBDF-TF-BTz表现出更高的介电常数 (4.22).
- PBDF-TF-BTz显示出改善的分子包装和可混合性,导致高效的激子解离和电荷传输.
- 基于PBDF-TF-BTz的OSC实现了17.01%和18.10%的功率转换效率,并添加了三元组件.
结论:
- 该研究强调了高透度材料在OSC中的重要性.
- PBDF-TF-BTz被确定为高性能有机太阳能电池的有前途的聚合物供体.
- 这项工作为开发先进光伏材料提供了有效的策略.
相关概念视频
P-N junction
567
A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
567
π Molecular Orbitals of 1,3-Butadiene
9.1K
Conjugated dienes have lower heats of hydrogenation than cumulated and isolated dienes, making them more stable. The enhanced stabilization of conjugated systems can be understood from their π molecular orbitals.
The simplest conjugated diene is 1,3-butadiene: a four-carbon system where each carbon is sp2-hybridized and has an unhybridized p orbital that contains an unpaired electron. According to molecular orbital theory, atomic orbitals combine to form molecular orbitals such that the number...
The simplest conjugated diene is 1,3-butadiene: a four-carbon system where each carbon is sp2-hybridized and has an unhybridized p orbital that contains an unpaired electron. According to molecular orbital theory, atomic orbitals combine to form molecular orbitals such that the number...
9.1K
Stability of Conjugated Dienes
3.4K
Introduction
A comparison of the enthalpies of hydrogenation of dienes reveals that conjugated dienes release less heat on hydrogenation, rendering them more stable than their nonconjugated analogs.
A comparison of the enthalpies of hydrogenation of dienes reveals that conjugated dienes release less heat on hydrogenation, rendering them more stable than their nonconjugated analogs.
3.4K


