基于溶剂的混合膜,用于对SO2进行超超选择性分离
Ping Zhang1, Zhuoheng Tu1, Zhihao Yan1
1Separation Engineering Research Center, Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, PR China.
Journal of hazardous materials
|September 13, 2023
概括
新的聚合物/深溶解剂 (DES) 混合膜有效地将二氧化硫 (SO2) 从 (N2) 和二氧化碳 (CO2) 中分离出来. 这些膜具有很高的SO2透性和选择性,显示出烟气脱硫的前景.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 二氧化硫 (SO2) 是主要的大气污染物,导致酸雨和烟雾.
- 深度环氧化溶剂 (DES) 正在成为气体捕获应用中的绿色溶剂.
- 对用于SO2分离的DES基膜的研究仍然有限.
研究的目的:
- 开发和评估用于选择性SO2分离的新型聚合物/DES混合膜.
- 研究这些膜在将SO2从N2和CO2中分离的性能.
- 探索这些膜在工业应用中的潜力,比如烟气脱硫.
主要方法:
- 使用聚乙烯化物 (PVDF) 和[Bmim]Br/乙烯甘醇 (DEG) 制造聚合物/DES混合膜.
- 气体透实验用于测量SO2,N2和CO2的透性和选择性.
- 谱分析以了解SO2和DES之间的相互作用.
- 在混合气体条件下对膜进行长期稳定性测试.
主要成果:
- 这种PVDF/DES混合膜实现了17480 Barrer.的高SO2透性.
- 获得了超高的SO2/N2选择性 (3690) 和SO2/CO2选择性 (211).
- 光谱分析显示,SO2与DES之间存在高度可逆的多点相互作用.
- 膜在分离混合SO2/CO2/N2气流时表现稳定,持续超过100小时.
结论:
- [Bmim]基于Br的DES是SO2膜分离的高度有效的介质.
- 聚合物/DES混合膜为SO2分离提供了一个有希望的,具有成本效益的解决方案.
- 这些膜显示出在烟气脱硫中应用的巨大潜力.
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