从石膏中通过微波热水晶相调节去除
Chengzhe Liao1,2, Xiaoqin Li3,4, Jun Li1,2
1School of Environment and Energy, Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling, South China University of Technology, Guangzhou, Guangdong, 510006, People's Republic of China.
Environmental science and pollution research international
|September 13, 2023
概括
微波热水处理有效地在10分钟内从石膏 (CG) 危险废物中去除超过99%的. 这种方法可以转化石膏,并大大减少有毒的泄漏,为工业废物提供了新的解决方案.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 石膏 (CG) 是来自盐和电工业的危险废物.
- 在CG中合的CrO42-很难用传统方法去除,这会给环境带来长期的风险.
- 现有的方法在石膏晶体中与稳定的CrO42-作斗争.
研究的目的:
- 开发一种有效的方法,从石膏中去除.
- 为了研究在去除过程中石膏的相变化.
- 为了评估处理后的毒性降低.
主要方法:
- 使用微波热水处理来处理CG.
- 最佳条件包括1:5的固体-液体比率,0.1M的硫酸,和110°C.
- 使用X射线衍射 (XRD) 分析石膏相变.
主要成果:
- 在最佳条件下,超过99%的在10分钟内从CG中去除.
- 59.8%的二水合物石膏转化为半水合物石膏.
- 的毒性从377.0毫克/升降至0.55毫克/升.
结论:
- 微波热水处理对于从CG中去除非常有效.
- 该过程促进石膏脱水和重金属释放.
- 这种方法为处理含有石膏的类似工业固体废物提供了有前途的解决方案.
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