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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Ionic Bonds00:42

Ionic Bonds

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Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
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Electrolysis03:00

Electrolysis

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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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相关实验视频

Updated: Jul 16, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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基于共价有机框架的固态电解质,电极材料和离子电池的分离器.

Youlong Zhu1, Qiaoshuang Bai1, Shan Ouyang1

  • 1Key Laboratory for Polymeric Composite & Functional Materials of Ministry of Education, IGCME, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, China.

ChemSusChem
|September 14, 2023
PubMed
概括

共价有机框架 (COF) 对先进的离子电池 (LIB) 显示出前景. 它们独特的多孔结构增强了离子储存和运输,为下一代储能提供了更好的容量和稳定性.

关键词:
共价有机框架是共价有机框架.电极材料 电极材料 电极材料离子电池的离子电池是什么分离器分离器分离器分离器分离器分离器固态电解质 固态电解质

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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 全球能源需求推动了可再生能源储能创新.
  • 离子电池 (LIB) 是至关重要的,但需要改进的材料容量和稳定性.
  • 共价有机框架 (COF) 为LIB增强提供了独特的特性.

研究的目的:

  • 审查LIB应用中COF的最新进展.
  • 突出COF在电解质,电极和分离器中的潜力.
  • 讨论基于COF的LIB面临的挑战和未来方向.

主要方法:

  • 在LIBs中对COF合成和应用的文献综述.
  • 对离子储存和运输相关的COF属性的分析.
  • 综合材料策略的总结涉及COFs.

主要成果:

  • COF具有高孔隙性,可调节的结构和可定制的功能.
  • 具有氧化还原活性位点和多孔通道的定制COF可以改善离子管理.
  • 在 (近乎) 固态电解质,电极材料和分离器中,COF是有效的.

结论:

  • 碳酸为下一代LIBs提供了一个有前途的材料.
  • 对COF的进一步研究可以克服目前储能方面的挑战.
  • COF为更高效,更稳定的离子电池技术提供了途径.