基于AgNbO3的多层电容器:异质离子替代工程实现了高能量存储性能
Ting Tang1, Dong Liu1, Qi Wang1
1School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China.
ACS applied materials & interfaces
|September 14, 2023
概括
研究人员通过使用异离子替代和多层电容技术,增强了用于先进电源设备的介电电容. 这实现了高能量存储密度和高效率,零余分极化和高分解强度.
科学领域:
- 材料科学 材料科学 材料科学
- 电气工程 电气工程
- 固态物理 固态物理
背景情况:
- 介电电容对于先进的高功率设备至关重要.
- 目前的局限性包括由于高残余极化和低分解强度而导致的低能量存储密度和效率.
研究的目的:
- 为了增强介电电容器的储能能力.
- 为了克服基于AgNbO3 (AN) 的电容器中残余极化和分解强度的局限性.
主要方法:
- 不同价值离子替代工程 (Sm3+替代Ag+).
- 多层电容 (MLC) 技术. 多层电容 (MLC) 技术.
- 分析相位转换和介电性质.
主要成果:
- 同时实现了大的最大极化,零残余极化和高分解强度.
- 在室温下,Sm3+替代引发了反铁电 (AFE) M2相.
- 在SmxAN+Mn MLCC (x=0.03) 中获得了优异的储能密度 (Urec ≈9.8 J·cm−3) 和功率密度 (P_D,max ≈34.8 MW·cm−3).
结论:
- 异价离子替代和MLCC技术为高性能介电电容器提供了一个可行的策略.
- 开发的AFE MLCC显示了先进的储能应用的巨大潜力.
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