在光学陷中捕获的热敏单个粒子的温度测量,使用拉曼光谱学
Yukai Ai1, Yong-Le Pan2, Gorden Videen2
1Department of Physics and Astronomy, Mississippi State University, Starkville, MS, USA.
Applied spectroscopy
|September 15, 2023
概括
研究人员开发了一种拉曼光谱法,用单壁碳纳米管和微米大小的钻石测量光学陷内部的温度. 这项技术揭示了陷中心及其空心梁之间的显著温度差异.
科学领域:
- 光学陷的捕捉方式
- 频谱学是一种光谱学.
- 纳米材料是一种纳米材料.
- 热分析是一种热分析.
背景情况:
- 光学陷对于操纵微/纳米粒子至关重要.
- 光学陷内的温度升高给粒子研究带来了挑战.
- 在光学陷内直接测量温度是很困难的.
研究的目的:
- 引入一种用于测量通用光学陷 (UOT) 内部温度的新方法.
- 用拉曼光谱来描述UOT内部的温度分布.
- 为了评估光学陷中的颗粒的加热速度.
主要方法:
- 使用拉曼光谱的单壁碳纳米管 (SWCNTs) 和微米大小的钻石 (MSDs).
- 测量拉曼移动以确定被困粒子的温度.
- 通过在UOT中的不同位置捕获颗粒来研究温度分布.
主要成果:
- 证明UOT中心比它的空心梁要冷得多.
- 量化颗粒表面温度变化从322K到830K,激光功率不同 (200-2950mW).
- 确定了UOT中心高热吸收粒子的18.3 ± 0.4 °C/100 mW的加热速率.
结论:
- 开发的拉曼光谱法准确地测量了光学陷中的温度分布.
- 这种技术对于研究材料特性,相位过渡和涉及被困粒子的化学反应是有价值的.
- 这些发现提供了对光学捕获系统内的热效应的关键见解.
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