玻璃成型液体的二点集体动力学 玻璃成型液体的二点集体动力学
Zhiqiang Shen1, Jan-Michael Y Carrillo1, Bobby G Sumpter1
1Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA.
The Journal of chemical physics
|September 15, 2023
概括
这项研究显示,在阿雷尼乌斯温度以下,形成玻璃的液体表现出缓慢的,中视镜动态. 这种非水力动力学集体动态的出现与结构放松和动态交叉的变化有关.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 材料科学是一种材料科学.
- 计算化学是一种计算化学.
背景情况:
- 形成玻璃的液体在玻璃过渡附近表现出复杂的动态.
- 了解结构和动态之间的关系对于材料科学至关重要.
研究的目的:
- 为了研究玻璃形成液体中的时空相关性.
- 为了探索低于阿雷尼乌斯温度的缓慢集体动态的出现.
主要方法:
- 使用了分子动力学模拟.
- 进行了密度-密度和压力-压力相关性的时空映射.
主要成果:
- 观察到结构放松时间在阿雷尼乌斯温度以下急剧增加.
- 缓慢的,非水力动力学集体动力学在中观尺度上出现.
- 确定了一种与局部结构相结合的远程,波数独立模式.
结论:
- 这项研究将 mesoscopic 动态的变化与动态交叉现象联系起来.
- 非水力动力学集体动力学在亚伦氏温度以下的玻璃形成液体的缓慢动力学中发挥着重要作用.
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