使用基于ZIF-8的甲基酸盐复合珠来有效地去除阴阳性染料:在批量和列系统中的性能评估
1Department of Chemical and Biological Engineering, American University of Sharjah, Sharjah, PO Box 26666, United Arab Emirates.
Chemosphere
|September 15, 2023
概括
研究人员开发了酸盐涂层的化物伊米达酸框架-8 (ZIF-8) 复合珠,用于有效的染料去除. 这些珠子在合成和工业废水中显示了马六合绿色染料的高吸附效率,提供了可重复使用和稳定的解决方案.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 水中的染料污染对环境和健康构成重大风险.
- 开发有效和可持续的方法来从废水中去除染料至关重要.
- 复合材料为污染物吸附提供了有希望的解决方案.
研究的目的:
- 为了合成和表征藻酸盐 (SA) 和焦化物伊米达酸框架-8 (ZIF-8) 复合珠.
- 为了评估SA@ZIF-8珠子的吸附效率,以去除马六合绿色染料.
- 评估这些珠子在处理真正的工业废水中的性能.
主要方法:
- 通过浸泡过程合成SA@ZIF-8复合珠.
- 使用XRD,FTIR,BET,TGA和SEM-EDX进行表征.
- 使用批量和固定床列反应器用合成和真实废水进行吸附研究.
主要成果:
- SEM证实了SA对ZIF-8的有效涂层.
- 在pH6下,在120分钟内达到95.5%的最大吸附率.
- 弗洛伊德利希的异温和PSO运动模型最好地描述了吸附过程.
- 从真正的工业废水样本中有效地去除染料.
结论:
- SA@ZIF-8复合珠在染料吸附方面表现出高效率和选择性.
- 复合珠子在稳定性,可重复使用性和实用性方面比粉末ZIF-8具有优势.
- 这些珠子代表着一个有希望的,广泛适用的工业废水处理技术.
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