表面活性,动力学,热力学和对选择的阴离子和阴离子染料在水流中的H3PO4功能化包上吸附的比较研究
Kaman Singh1, Utkarsh Dixit2, Madhu Lata2
1Surface Science Laboratory, Department of Chemistry, School of Physical and Decision Science, Babasaheb Bhimrao Ambedkar University (A Central University), Lucknow, Uttar Pradesh, 226025, India. singh.kaman@bbau.ac.in.
Environmental science and pollution research international
|September 17, 2023
概括
热化学激活包油 (TCAB) 有效地从废水中去除阴离子和阴离子染料. 这种可持续吸附剂在多个循环中显示出高容量和可重复使用性,为染料污染处理提供了一个有希望的解决方案.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 水处理技术 水处理技术
背景情况:
- 水体中的染料污染对水生生物构成毒性风险,原因是芳香化合物的反抗性.
- 在环境排放之前,有效处理含有染料的废水至关重要,以减轻生态损害.
研究的目的:
- 合成和特征化热化学活性 (TCAB) 作为一种新型吸附剂,用于去除阴离子和阴离子染料.
- 研究TCAB对各种染料分子的吸附性能和机制.
- 评估TCAB在染料废水处理中的可重复使用性和实际应用性.
主要方法:
- 巴加斯在600°C进行热处理,并与55%的H3PO4功能化,以创建TCAB.
- 使用FT-IR,SEM,XRD,zeta潜力,BET和PZC技术进行了TCAB的表征.
- 进行了吸附实验,以评估在不同条件下 (TCAB剂量,染料度,pH,离子强度,尿素,温度) 的染料去除效率,并适应动力和异热模型.
主要成果:
- TCAB对染料具有很高的吸附能力,其中甲基红色 (185 mg/g) 和沙夫兰素 (178 mg/g) 的吸收率最高.
- 吸附动力学遵循伪二阶模型,平衡数据与弗洛伊德利希等温模型保持一致.
- 热力学分析表明自发和外热吸附过程,TCAB在三个再生周期中保持了显著的吸附能力.
结论:
- 热化学激活包油 (TCAB) 是一种高效且可重复使用的吸附剂,用于广泛的阴离子和阴离子染料.
- 这项研究提供了对功能化包油的吸附性质的宝贵见解,增强了其用于工业废水处理的潜力.
- TCAB为减轻水生环境中染料污染提供了一种可持续和高效的解决方案.
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