通过在干燥过程中通过液相浸修饰的活性炭的自发燃烧特性
Qing-En Li1, Bing J Zhang1, Shu-Shen Lyu1
1School of Materials Science and Engineering, Guangdong Engineering Center for Petrochemical Energy Conservation, The Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, Sun Yat-Sen University, Xiaoguwei Island, Panyu District, Guangzhou 510006, P. R. China.
ACS omega
|September 18, 2023
概括
改性活性炭的安全干燥需要了解其燃烧风险. 这项研究发现,改性活性炭在175-180°C之间点燃,热量集中在燃烧室中心,这对于防止工业火灾至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 安全工程安全工程
背景情况:
- 在干燥过程中活性炭自发燃烧会带来重大安全风险.
- 液相浸是活性炭的常见修改方法.
研究的目的:
- 为了研究用4-amino-1,2-butanediol修饰的活性炭的自燃特性.
- 为了确定修改活性炭的点火温度和激活能量.
- 为了确定安全操作的关键干燥温度.
主要方法:
- 物理属性和表面功能组的表征.
- 使用GB/T20450-2006,TG-DTG和TG-MS来确定点火温度.
- 通过热力学分析计算激活能量.
- 在自己设计的平台上,在各种干燥温度下进行自发燃烧实验.
主要成果:
- 修改减少了BET表面积,毛孔总体积和含氧的功能组.
- 在修改后,点火温度略有增加 (例如,~483°C~489°C).
- 激活能量增加了35kJ/mol的修饰活性炭.
- 燃烧开始在175°C和180°C之间,热量集中在中心.
结论:
- 改性活性炭表现出更高的激活能量,表明增加了热稳定性.
- 在干燥过程中自燃的临界温度范围为175-180°C.
- 了解热量的积累对于防止活性炭干燥过程中的火灾至关重要.
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