在离子电池中的性能退化分析基于块状颗粒扩散模型
Pengya Fang1, Anhao Zhang2, Xiaoxiao Sui2,3
1School of Aero Engine, Zhengzhou University of Aeronautics, Zhengzhou 450015, China.
ACS omega
|September 18, 2023
概括
这项研究引入了块状颗粒扩散模型来分析离子电池的降解. 该模型在现实条件下准确预测性能下降和内部状态演变.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 电池技术 电池技术
背景情况:
- 离子电池性能降低会影响故障诊断和安全.
- 了解降解机制对于电池管理至关重要.
研究的目的:
- 提出一种研究离子电池降解模式的方法.
- 建立内部和外部参数之间的结构-活动关系.
- 为了实时对电池性能恶化的定量分析.
主要方法:
- 在使用CC-CV充放电模式的新欧洲驾驶周期 (NEDC) 条件下进行了循环寿命测试.
- 开发了一种块状粒子扩散模型.
- 使用Levenberg-Marquardt (L-M) 算法进行模型参数识别.
主要成果:
- 分析了外部宏观特征参数的变化.
- 在不同的老化条件下确定欧姆值,激活和度损失.
- 揭示了电池退化过程中的内部状态演变.
结论:
- 块状粒子扩散模型全面解释了离子电池性能降低的内部机制.
- 拟议的方法为实时定量分析电池退化提供了一种新的方法.
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