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在成熟过程中从Camellia oleifera的果中获得的红素和红素碳水化合物复合物的结构变化
Xichuang Cheng1, Ruxia Ning1, Pengfei Li2
1Engineering Research Center of Forestry Biomass Materials and Bioenergy (Ministry of Education), Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, China.
International journal of biological macromolecules
|September 18, 2023
概括
研究了Camellia oleifera果 (CFS) 红素和红素碳水化合物复合体 (LCC) 在成熟过程中的结构变化. 慢性疲劳症的线素显示出增加的分子量和抗氧化潜力,为生物质预处理提供了洞察力.
科学领域:
- 生物质的价值化 生物质的价值化
- 纤维素化学 纤维素化学
- 植物生物化学 植物生物化学
背景情况:
- 卡梅利亚橄花 (Camellia oleifera) 果 (CFS) 是石油生产中的易于获得的纤维素废物.
- 了解在水果成熟期间的红素和红素碳水化合物复合物 (LCC) 结构动态对于生物质利用至关重要.
- 在CFS红素和LCC结构的变化可以影响生物质加工和潜在的应用.
研究的目的:
- 在水果成熟过程中系统地表征CFS素和LCC的结构变化.
- 为了研究CFS木质素分数的分子量,结合类型和S/G比率的变化.
- 为了确定主要的LCC链接,并评估CFS分量的抗氧化特性.
主要方法:
- 从30天成熟期内收获的CFS中分离和表征原生素 (MWL) 和脱素 (DEL) 分数.
- 对素分子重量,β-O-4'链接和S/G比率的分析.
- 在LCC-AcOH分数中识别红素-碳水化合物链接,并评估抗氧化能力.
主要成果:
- 在CFS成熟过程中,MWL和DEL分量的分子量始终在增加.
- 慢性硬化症的基因表现出高丰度的β-O-4'链接和低的S/G比率 (<0.6).
- 在MWL,DEL和LCC-AcOH分数中的β-O-4'链接最初增加,然后减少;乙烯和基化物是主要的LCC链接.
- LCC-AcOH 分数显示出显著的抗氧化能力.
结论:
- 成熟显著改变了CFS素和LCC结构,影响了它们的特性.
- 拟议的CFS素结构图提供了对成熟依赖的变化的洞察力.
- 来自CFS的LCC分量显示出作为天然抗氧化剂的前景,突出了生物质价值化潜力.
- 了解这些结构功能关系对于优化细胞生物质预处理策略至关重要.
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