具有可变溶剂极性的共价定性键稳定性的趋势取决于易斯电子对系统中的电荷转移

Rabindranath Lo1,2, Debashree Manna1, Vijay Madhav Miriyala1,2

  • 1Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, v.v.i., Flemingovo nám. 2, Prague 6 16000, Czech Republic. pavel.hobza@uochb.cas.cz.

概括

溶剂中的dative键的稳定性取决于电荷转移. 充足的电荷转移通过增加溶剂极性来增强复合体的稳定性,但充足的电荷转移没有相反的效果.

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