岩石上的甲醇:绿色生转化促进了甲的氧化
Orion Farr1,2, Nil Gaudu2, Gregoire Danger3
1CNRS, CINaM, Aix-Marseille Univ, 13009 Marseille, France.
Journal of the Royal Society, Interface
|September 20, 2023
概括
像绿这样的反应性矿物质可以氧化甲,类似于酶. 这一发现揭示了一条新的碳循环路径,并揭示了早期生命的起源.
科学领域:
- 地质化学 地质化学
- 生物地质化学生物地质化学
- 天体生物学 天体生物学
背景情况:
- 反应性矿物质中的金属离子和生物酶辅因子之间存在共享的协调几何.
- 这表明无生物矿物学与生物代谢之间存在潜在的机械和进化联系.
- 反应性Fe (II) /Fe (III) 矿物质,就像在无氧沉积物和早期地球海洋中发现的绿色一样,表现出八面体协调.
研究的目的:
- 为了研究矿物介导甲氧化的潜力.
- 探索绿色生矿物学与可溶性甲单氧化酶 (sMMO) 的二铁中心之间的平行.
- 为了阐明以前未知的碳循环机制.
主要方法:
- 在绿色生的存在下对甲氧化的实验观察.
- 矿物转化产品的分析 (莱皮多克罗和磁铁).
- 氧化产品的识别,包括甲醇和化碳化合物.
主要成果:
- 观察到甲氧化与绿色生氧化到勒皮多克罗和磁铁同时发生.
- 该过程模仿了sMMO的基因介导甲氧化机制.
- 在海水的存在下产生甲醇和化碳化合物.
结论:
- 已经确定了甲 (CH4) 氧化的天然地化学途径.
- 这一途径代表了在现代和古代环境中显著的,以前未知的碳循环机制.
- 矿物介导反应为我们提供了关于有机化合物的合成的见解,这些化合物对生命起源至关重要.
相关概念视频
Metabolism of Chemolithotrophs
40
Chemolithotrophs are microorganisms that obtain energy by oxidizing inorganic molecules such as hydrogen gas (H₂), ammonia (NH₃), reduced sulfur compounds (H₂S, S²⁻), and ferrous iron (Fe²⁺). Unlike heterotrophic organisms that rely on organic carbon, chemolithotrophs transfer electrons from these inorganic donors to the electron transport chain (ETC), generating a proton motive force (PMF) that drives ATP synthesis through oxidative phosphorylation.
40
Corrosion
25.0K
The degradation of metals due to natural electrochemical processes is known as corrosion. Rust formation on iron, tarnishing of silver, and the blue-green patina that develops on copper are examples of corrosion. Corrosion involves the oxidation of metals. Sometimes it is protective, such as the oxidation of copper or aluminum, wherein a protective layer of metal oxide or its derivatives forms on the surface, protecting the underlying metal from further oxidation. In other cases, corrosion is...
25.0K
Microbial Nutrition
57
Organisms exhibit remarkable metabolic diversity, categorized based on how they acquire energy and carbon. These strategies enable survival in various ecological niches and are essential for maintaining energy flow and nutrient cycling within ecosystems.Energy and Carbon SourcesOrganisms are classified as phototrophs or chemotrophs based on energy acquisition. Phototrophs use light as their energy source, while chemotrophs rely on oxidizing chemical compounds. Further differentiation arises...
57
Overview of Nitrogen Metabolism
8.1K
Nitrogen is a very important element for life because it is a major constituent of proteins and nucleic acids. It is a macronutrient, and in nature, it is recycled from organic compounds and stored in the form of ammonia, ammonium ions, nitrate, nitrite, or nitrogen gas by many metabolic processes. Many of these metabolic processes are carried out only by prokaryotes.
The largest pool of nitrogen available in the terrestrial ecosystem is gaseous nitrogen (N2) from the air, but this...
The largest pool of nitrogen available in the terrestrial ecosystem is gaseous nitrogen (N2) from the air, but this...
8.1K
Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate
11.8K
Alkenes can be dihydroxylated using potassium permanganate. The method encompasses the reaction of an alkene with a cold, dilute solution of potassium permanganate under basic conditions to form a cis-diol along with a brown precipitate of manganese dioxide.
11.8K
Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids
5.9K
Diols are compounds with two hydroxyl groups. In addition to syn dihydroxylation, diols can also be synthesized through the process of anti dihydroxylation. The process involves treating an alkene with a peroxycarboxylic acid to form an epoxide. Epoxides are highly strained three-membered rings with oxygen and two carbons occupying the corners of an equilateral triangle. This step is followed by ring-opening of the epoxide in the presence of an aqueous acid to give a trans diol.
5.9K


