用于Li-S电池的硫/碳共聚合物阴极的表征:一个联合的实验和Raman光谱学研究
Rana Kiani1, Matthias Steimecke1, Marah Alqaisi1
1Institute of Chemistry, Martin Luther University Halle-Wittenberg Von-Danckelmann-Platz 4 06120 Halle (Saale) Germany pouya.partovi-azar@chemie.uni-halle.de.
RSC advances
|September 20, 2023
概括
新的拉曼光谱方法区分硫电池阴极材料. 具有较长硫链的聚硫-1,3-二异乙 (S/DIB) 共聚合物表现出独特的S-S拉伸振动,有助于材料的特性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 计算化学计算化学
背景情况:
- 硫电池具有高的理论能量密度,但需要先进的阴极材料.
- 硫/碳共聚合物是水晶硫的有希望的替代品,可以减轻穿效应.
- 聚硫-1,3-二异乙) (S/DIB) 共聚物正在研究提高电池性能.
研究的目的:
- 开发一种基于硫链长度区分S/DIB共聚物的方法.
- 为了将拉曼光谱信号与硫/碳阴极的结构特征相关联.
- 为硫电池新型阴极材料的表征提供见解.
主要方法:
- 结合 *ab initio* 拉曼光谱模拟与实验性的拉曼测量.
- 在400-500厘米-1频率范围内分析了拉曼光谱.
- 在S/DIB共聚物的硫链长度函数中研究了S-S拉伸振动.
主要成果:
- 具有短和长硫链的S/DIB共聚物表现出明显的拉曼活性.
- 在400-500厘米-1范围内的特定拉曼信号对应于S-S拉伸振动.
- 这种特征信号仅在具有较长硫链的共聚物中观察到.
结论:
- 拉曼光谱学可以有效地根据硫链长度区分S/DIB共聚物.
- 在400-500厘米-1范围内存在S-S拉伸振动,表明硫链较长.
- 这种方法有助于识别和表征硫/碳共聚合物,在电池应用中含有不同含量的硫.
相关概念视频
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A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
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The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
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