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高效的近红外固体溶液光体具有出色的热稳定性和可调节的光谱,用于PC-LED光源,用于NIR光谱应用
Tianchun Lang1, Qunyang Zhao1, Xiaolong Jing1,2
1College of Materials Science and Engineering, Chongqing University of Arts and Sciences, Chongqing, 402160, China.
Physical chemistry chemical physics : PCCP
|September 20, 2023
概括
新的近红外 (NIR) 固态光体显示出出色的光学性能和热稳定性. 这些Cr3+激活材料显示了NIRLED的潜力,并增强了光合作用细菌的活动.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 光物理学的光学物理学
背景情况:
- 近红外 (NIR) 发光材料对于开发先进的NIR发光二极管 (NIR LED) 至关重要.
- 激活Cr3+为NIR发射应用提供了独特的光物理特性.
研究的目的:
- 为了合成和描述一系列Cr3+激活的NIR发射固体溶液,Gd1-xLu-xAl1-ySc-y) 3BO40.01Cr3+.
- 调查Lu3+-Sc3+共兴奋剂对这些光物的光学和热性质的影响.
- 评估这些在NIR功率LED (pc-LED) 中的性能及其在夜视,生物识别和增强细菌光合作用方面的潜在应用.
主要方法:
- 通过共同替代方法进行固态合成.
- 光发光光谱学用于光学表征.
- 制造和测试NIR pc-LED. 的生产和测试.
主要成果:
- 成功合成了Gd1-xLux(Al1-yScy)3(BO3)4:0.01Cr3+的.
- 实现了93.6%的高内部量子效率 (IQE).
- 观察到一半最大 (FWHM) 的全宽度从128nm扩大到196nm,以及从747nm的发射红移到866nm,随着Lu3+-Sc3+兴奋剂的增加.
- 证明了出色的光发光热稳定性,具有高达150°C的零热灭.
- 制造的NIR pc-LED实现了46mW的输出功率和37%的电光效率.
结论:
- 开发的GLASB:Cr3+光体具有卓越的光学性能和NIR发射的热稳定性.
- 这些光素对NIRLED,夜视和生物识别有很大的希望.
- 通过匹配细菌和光采集蛋白的吸收,NIR发射显示了改善细菌光合作用的应用潜力.
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