可拉伸,强,可回收的化物弹性体,基于动态共价相互作用
Hafeez Ur Rehman1,2, Mikael S Hedenqvist3, Yujie Chen1
1State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China.
ACS applied materials & interfaces
|September 20, 2023
概括
研究人员使用动态共价键开发了一种新的可回收弹性体. 这种先进的聚合物在几分钟内表现出100%的自我愈合,并在几个小时内降解,为传统塑料提供了一个可持续的替代品.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 可持续化学 可持续化学
背景情况:
- 目前的合成聚合物生产和处置方法是不可持续的.
- 动态共价键为设计先进的分子结构提供了一个可逆的特性.
- 这些纽带使得可回收和机械互锁材料的创造成为可能.
研究的目的:
- 开发一种基于螺旋体的新型弹性体网络.
- 将自我愈合,回收和降解能力纳入弹性质.
- 为了解决目前不可持续的聚合物技术的局限性.
主要方法:
- 合成基于螺旋体的弹性体网络,利用动态共价键.
- 在各种溶液条件下 (H2O,HCl,NaOH) 评估自我愈合特性.
- 根据结合类型,pH值和共聚物网络评估水解性降解速率.
- 在多次回收循环后测试机械性能.
主要成果:
- 在10-20分钟内实现了100%的自我愈合性能.
- 在测试条件下,机械性能在1-1.4 MPa之间.
- 根据具体参数,水解性降解发生在4-11小时内.
- 材料在连续五次回收循环后保持了良好的机械性能.
结论:
- 开发的基于螺旋体的弹性体表现出显著的自我愈合,降解和回收能力.
- 该材料为聚合物应用和包装提供了一个有希望的可持续替代品.
- 动态共价键的可逆性质是实现这些理想材料性质的关键.
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