使用热重力测量分析的简单方法量化使用寿命结束的离子电池中的石墨
Luis Arturo Gomez-Moreno1, Anna Klemettinen1, Rodrigo Serna-Guerrero1
1Department of Chemical and Metallurgical Engineering, School of Chemical Engineering, Aalto University, P.O. Box 16200, Espoo, Aalto 0076, Finland.
iScience
|September 21, 2023
概括
一种新的热重力测量分析方法准确地测量了电池材料中的石墨含量. 这种简单,廉价的技术为回收和材料分析提供了快速的石墨估计.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 分析化学 分析化学
背景情况:
- 精确的石墨含量确定对于电池材料的表征和回收至关重要.
- 现有的石墨分析方法可能是复杂和昂贵的.
研究的目的:
- 开发一种新的,具有成本效益的热重力测量分析 (TGA) 方法,用于量化电池材料混合物中的石墨.
- 用人工和工业电池废弃物样本验证TGA方法.
主要方法:
- 使用热重力测量分析 (TGA),利用高温下Li过渡金属氧化物和石墨之间的热化学反应.
- 在TGA期间的阴极质量损失和人工混合物的石墨含量之间建立了线性相关性.
- 使用工业黑质量样本证实了该方法的适用性,并分析了错误来源.
主要成果:
- 在人工样本中观察到阴极质量损失和石墨含量之间存在明显的线性相关性.
- 工业电池废弃物的TGA配置文件与人工系统的TGA配置文件相似,证实了该方法的适用性.
- 该TGA方法证明了能够区分单个和多个Li-金属氧化物阴极的能力.
结论:
- 开发的TGA方法提供了一种简单,廉价和快速的方法来估计电池材料中的石墨含量.
- 虽然精度受活性成分混合物和杂质的影响,但该方法对于快速评估石墨有价值.
- 这种技术为现有的石墨特征表征方法提供了切实可行的替代方案.
相关概念视频
Gravimetry: Overview
6.0K
Gravimetric analysis is a quantitative method where the analyte is isolated and weighed directly or after conversion into a substance of known composition. Gravimetric analysis can be classified as precipitation, electrogravimetry, volatilization, and particulate gravimetry, based on the method used to isolate the analyte.
In precipitation gravimetry, the analyte is converted into a precipitate and weighed. For example, the silver content in a sample can be estimated by precipitating and...
In precipitation gravimetry, the analyte is converted into a precipitate and weighed. For example, the silver content in a sample can be estimated by precipitating and...
6.0K
Electrogravimetric Analysis: Overview
262
Electrogravimetric analysis measures the weight of an analyte deposited electrolytically onto a suitable working electrode. This method involves applying a potential to a pre-weighed electrode submerged in a solution, which results in the desired substance being deposited through reduction at the cathode or oxidation at the anode. The electrode's weight is recorded after deposition, and the difference in weight gives the analyte's weight in the solution.
To test the completeness of the...
To test the completeness of the...
262
Volatilization
417
Volatilization gravimetry is an analytical technique that measures the mass lost due to the volatilization of the substance. This technique is used to estimate the amount of volatile material in a sample. To perform this method, heat a known amount of the sample to a high temperature in a crucible or other suitable vessel. The volatile substance in the sample evaporates, and the vapor is completely expelled from the crucible either by heating the sample or bubbling a stream of inert gas through...
417


