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Updated: Jul 16, 2025

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

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在Ceria支持的Pt粒子中对电子金属支相互作用的系统性表征

Pablo Castro-Latorre1, Konstantin M Neyman1,2, Albert Bruix1

  • 1Departament de Ciència de Materials i Química Física, Institut de Quimica Teòrica i Computacional (IQTCUB), Universitat de Barcelona, 08028 Barcelona, Spain.

The journal of physical chemistry. C, Nanomaterials and interfaces
|September 22, 2023
PubMed
概括

本研究介绍了一种计算方法,以表征催化剂中的电子金属支相互作用. 这些发现揭示了这些相互作用如何影响原子对基支持的反应性,使得有针对性的催化剂设计成为可能.

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Electron Configuration of Multielectron Atoms

The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
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CFT focuses on...
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Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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