在有孔的硬碳上,工程超薄碳层增强了高初始库伦比效率的储存
Dejian Cheng1,2, Zhenghui Li2, Minglu Zhang2
1Research Institute of Materials Science, South China University of Technology, and Key Laboratory of Polymer Processing Engineering (South China University of Technology), Ministry of Education, Guangzhou 510640, China.
ACS nano
|September 22, 2023
概括
这项研究通过将硬碳涂上超薄的石墨化碳层来增强离子电池阳极. 这提高了初始库伦比克效率 (ICE) 和电化学性能,以获得更好的电池技术.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 硬碳 (HC) 是离子电池 (NIB) 的常见阳极.
- 的多孔结构导致初始库伦比效率 (ICE) 较低.
研究的目的:
- 开发用于NIB中的HC阳极的表面修改方法.
- 为了提高HC阳极的ICE和电化学性能.
主要方法:
- 用 bis ((cyclopentadienyl) 尼克尔和葡萄糖碳球,涂上 HC 带有石墨化的超薄碳层.
- 使用一个二氧化层来帮助涂层过程.
- 制造一种被超薄碳层复合材料 (PCS@V@C) 覆盖的多孔碳材料.
主要成果:
- 实现了ICE从47.1%增加到85.3%.
- 增强的特定容量从155.3到216.7mAhg-1在0.1Ag-1.1时.
- 证明了出色的速率能力 (140.3 mA h g-1 在 10 A g-1 时) 和循环稳定性 (225.6 mA h g-1 在 300 个循环后).
结论:
- 超薄的碳层促进稳定的固体电解质介相 (SEI) 膜的形成.
- PCS@V@C复合材料为高性能NIB阳极材料提供了可行的表面修饰.
- 这种方法显著提高了离子电池的特定容量和ICE.
相关概念视频
Energy Stored in a Capacitor
When an archer pulls the string in a bow, he saves the work done in the form of elastic potential energy. When he releases the string, the potential energy is released as kinetic energy of the arrow. A capacitor works on the same principle in which the work done is saved as electric potential energy. The potential energy (UC) could be calculated by measuring the work done (W) to charge the capacitor.
Energy Stored in Capacitors
A parallel plate capacitor, when connected to a battery, develops a potential difference across its plates. This potential difference is key to the operation of the capacitor, as it determines how much electrical energy the capacitor can store.
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
MOS Capacitor
A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
Electrochemical Cells
Electrochemical cells are systems that convert chemical energy into electrical energy or use electrical energy to drive chemical reactions. They consist of two electrodes in contact with an electrolyte, where redox reactions enable electron transfer. Most electrochemical cells include two half-cells connected by an external wire for electron flow and a salt bridge for ion flow. The salt bridge contains an electrolyte solution and maintains charge neutrality by allowing ions—not electrons—to...


