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Updated: Jul 16, 2025

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
08:46

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides

Published on: July 26, 2018

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在弱核友环境中由4-O-基团介导的β-l-Rhamnosylation和β-d-Mannosylation

Yongliang Zhang1, Changsheng Chen1, Yongtao Gao1

  • 1National Glycoengineering Research Center and Shandong Key laboratory of Carbohydrate Chemistry and Glycobiology, Shandong University, 72 Binhai Rd Qingdao 266237, China.

Organic letters
|September 22, 2023
PubMed
概括

这项研究展示了一种使用4-O-acyl组和弱协调性离子实现β-rhamnosylation和β-mannosylation的立体选择性糖化新方法. 2,3-欧托碳酸盐组促进了这一过程,并且可以很容易地去除.

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