热处理温度对无形NbCo1.1Sn结晶行为和微观结构演化的影响
Chanwon Jung1,2, Siyuan Zhang2, Kyuseon Jang1
1Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea.
ACS applied materials & interfaces
|September 22, 2023
概括
在893 K温度下对无形NbCoSn合金进行热处理,可以产生更细的颗粒和Heusler纳米沉,从而降低导热率. 这种纳米结晶是先进热电材料的关键.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 固态物理 固态物理
背景情况:
- 通过热处理对半Heusler化合物进行纳米结构,可以提供可定制的材料特性.
- 了解无形前体结晶对于优化纳米结构材料至关重要.
研究的目的:
- 研究无形NbCo1.1Sn合金在783K和893K的结晶行为.
- 确定热温度对相位形成和微观结构的影响.
- 分析微观结构对格子导热性的影响.
主要方法:
- 传输电子显微镜 (TEM) 用于微观结构分析.
- 原子探头断层扫描 (APT) 用于纳米级的组成和结构调查.
- 德拜-卡拉威模型用于导热分析.
主要成果:
- 在893K的化产生了比783K更细的粒度结构,因为核化速率更高.
- 在这两种温度下,半Heusler相占主导地位;在893 K时,Heusler相只形成.
- 在893K的低格子导热率被归因于Heusler纳米沉,而不仅仅是细粒.
结论:
- 较高的回火温度促进了NbCoSn合金中的更细微的纳米结晶和特定相形成.
- 豪斯勒纳米沉物显著影响晶格导热率,提供了一条提高热电性能的途径.
- 这项研究为设计通过受控纳米结晶改善热电性质的无形合金提供了关键的见解.
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