在部分凝聚过程中,紧动力学和多重滴滴生成
1ThAMeS Multiphase, Department of Chemical Engineering, University College London, London WC1E 7JE, United Kingdom.
Physical review letters
|September 22, 2023
概括
部分凝聚发生在液体气由于雷利-高原不稳定性而被断时. 表面活性剂改变滴滴形成和稀释动态,在较高度下产生多个滴滴.
科学领域:
- 流体动力学 流体动力学
- 接口现象 接口现象
- 类风病学 类风病学 类风病学
背景情况:
- 部分凝聚是流体动力学中常见的现象.
- 了解滴滴动态对于各种工业应用至关重要.
研究的目的:
- 调查部分凝聚过程中液体气被断的机制.
- 分析表面活性剂对滴滴形成和断裂动态的影响.
主要方法:
- 使用掉落撞击实验进行实验调查.
- 数字模拟用于模拟流体行为.
- 分析部瘦身方案 (惯性和惯性粘性).
主要成果:
- 雷利-普拉托的不稳定性驱动气扣掉,当高度到子比率超过一个.
- 表面活性剂减弱液体气,并促进多滴滴产生.
- 从惯性 (I) 转变为惯性粘性 (IV) 模式的部变薄.
- 在较高的表面活性剂度下,中间方案加速了稀释.
结论:
- 这项研究阐明了雷利-普拉托不稳定在部分凝聚中的关键作用.
- 表面活性剂显著改变滴水分解路径,使得可以控制滴水生成.
- 已识别出不同的稀释模式,为界面流的物理提供了洞察力.
相关概念视频
Pinching-off of Coated Vesicles
3.2K
Vesicle budding is orchestrated by distinct cytosolic proteins such as adaptor proteins, coat proteins, and GTPases. To initiate vesicle budding, membrane-bending proteins containing crescent-shaped BAR domains bind to the lipid heads in the bilayer and distort the membrane to form a protein-coated vesicle bud. Adaptors proteins such as AP2 for clathrin-coated vesicles can nucleate on the deformed membrane. Finally, coat proteins such as clathrin or COPI and COPII assemble into a coat forming...
3.2K
Precipitate Formation and Particle Size Control
809
In precipitation gravimetry, the precipitating agent should react specifically or selectively with the analyte. While a specific reagent reacts with the analyte alone, a selective reagent can react with a limited number of chemical species.
The obtained precipitate should be either a pure substance of known composition or easily converted to one by a simple process, such as ignition or drying. In addition, the precipitate should be insoluble and easily filterable. In general, filterability...
The obtained precipitate should be either a pure substance of known composition or easily converted to one by a simple process, such as ignition or drying. In addition, the precipitate should be insoluble and easily filterable. In general, filterability...
809
Excess Pressure Inside a Drop and a Bubble
1.7K
The shape of a small drop of liquid can be considered spherical, neglecting the effect of gravity. This drop can further be considered as two equal hemispherical drops put together due to surface tension. The forces acting on the spherical drop are due to the pressure of the liquid inside the drop, the pressure due to air outside the drop, and the force due to the surface tension acting on the two hemispherical drops.
1.7K
Colloidal precipitates
615
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
615
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
333
Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the...
333


