一个基于离子选择性电极阵列的多离子干扰解模型
Zhancheng Mai1, Shaoqiu Xiao1, Wei Zhang2
1School of Electronics and Information Technology, Sun Yat sen University, Panyu District, Guangzhou City, Guangdong Province, China. wangkai23@mail.sysu.edu.cn.
Analytical methods : advancing methods and applications
|September 23, 2023
概括
本研究引入了一种新的比例系数模型,以改进固体接触离子选择性电极 (SC-ISEs),以准确检测多离子. 该模型增强了选择性,并减少了复杂样本中的信号漂移.
科学领域:
- 电化学 电化学 电化学
- 分析化学 分析化学
- 传感器技术 传感器技术
背景情况:
- 固体接触离子选择性电极 (SC-ISEs) 与传统类型相比具有优势,但受弱选择性和信号漂移的影响.
- 现有的人工神经网络 (ANN) 方法和数值模型在校准,计算成本或复杂性方面存在局限性.
- 对于SC-ISEs来说,需要实用,经济和强大的模型来克服来自多个离子的干扰.
研究的目的:
- 为SC-ISEs开发一种新的比例系数模型,并采用动态校正程序.
- 在多个干扰离子的存在下,提高SC-ISEs的选择性和稳定性.
- 为了验证模型的性能,使用多通道SC-ISE阵列进行现实世界样本分析.
主要方法:
- 提出了一种包含估计响应表面方法的比例因子模型来解决非线性方程.
- 实施了可扩展的动态校正程序,以提高稳定性和适应不同ISE的适应性.
- 设计并使用多通道SC-ISE阵列进行实验验证和多离子解.
主要成果:
- 该模型精确地提取了多个目标离子的度,尽管存在多离子干扰.
- 与传统方法相比,需要更少的校准实验.
- 在一个案例研究中证明了,,和离子的成功脱.
- 验证了多离子检测系统对现实世界水样的准确性.
结论:
- 拟议的比例系数模型为提高SC-ISE性能提供了实用和经济的解决方案.
- 动态校正程序增强了SC-ISEs对复杂样品的稳定性和适用性.
- 开发的多通道SC-ISE阵列系统有效地用于环境监测中精确的多离子检测.
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