发光兰化物混合N-phthaloylglycinate和甲酸协调聚合物:结构和光学特性
Joaldo G Arruda1, Wagner M Faustino1, Rafaela B P Pesci1
1Departamento de Química, Universidade Federal da Paraíba, João Pessoa, PB, Brazil.
Luminescence : the journal of biological and chemical luminescence
|September 25, 2023
概括
使用N-phthaloylglycine和terphthalic连接体的新型兰坦化协调聚合物具有高颜色纯度和刚性. 这些材料为开发先进的发光功能材料提供了一个有前途的平台.
科学领域:
- 材料科学 材料科学 材料科学
- 无机化学 无机化学
- 晶体学 晶体学是指结晶学.
背景情况:
- 兰化物协调聚合物 (CPs) 由于其独特的发光特性而引起人们的兴趣.
- 混合碳酸盐配体提供了多功能协调模式和结构多样性.
- 开发具有增强发光和结构稳定的新型CP对于先进材料至关重要.
研究的目的:
- 合成和表征一种新型的丹化物混合碳酸盐协调聚合物.
- 研究合成化合物的结构特征和发光特性.
- 探索这些材料在发光功能应用中的潜力.
主要方法:
- 使用兰化酸盐,N-phthaloylglycine和铁酸的兰化协调聚合物的溶热合成.
- 单晶X射线衍射用于结构确定.
- 发光光谱学用于分析排放特性和能量传递机制.
主要成果:
- 一个新的类型的兰化物混合碳酸盐CP与公式{[Ln2(phthgly) 4(bdc) ((H2O) 6) · ((H2O) 4} ∞成功合成了Eu3+和Gd3+.
- 这些CP具有对称的双核单元,具有多种协调模式的碳酸盐联结体和广泛的键,导致刚性结构.
- 含有欧的CP (1) 呈现出具有高颜色纯度的狭窄红色发射带,证明了有效的分子内能量从连接物转移到Eu3+离子.
结论:
- 合成的胺协调聚合物代表了一种具有特殊结构刚性和发光特性的新型材料类.
- 基于Eu3+的CP显示有前途的发光特性,适合先进的功能材料.
- 这些发现突显了混合碳酸盐联结体在设计复杂的胺基发光材料中的潜力.
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