优化,动力学和异温研究 甲基化从模拟溶液中去除,使用酸盐衍生物
Manar El-Sayed Abdel-Raouf1, Reem Kamal Farag1, Ahmed A Farag1
1Egyptian Petroleum Research Institute, 1 Ahmed El-Zomor, Nasr City 11727, Cairo, Egypt.
ACS omega
|September 25, 2023
概括
基托桑衍生物被修改并测试了从水中去除甲蓝 (MB) 染料. 基托桑与甲/甲基二 (?? 烯胺) 交联显示出最高的吸附能力,证明了有效的染料去除和可重复使用.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 聚合物科学 聚合物科学
背景情况:
- 织废水由于排放危险的阴阳性染料,如甲蓝 (MB),造成了严重的环境危害.
- 奇托是一种生物聚合物,由于其功能组和生物降解性,具有开发有效吸附剂的潜力.
- 之前的研究已经探讨了用于去除重金属的奇托桑衍生物,表明它们的多功能性.
研究的目的:
- 为了研究素修饰新型产品的吸附性能,用于从水溶液中去除甲蓝 (MB) 染料.
- 描述已制备的奇托衍生物,并评估它们的吸附能力,可重复使用性和膨胀行为.
- 阐明MB染料对改性酸盐吸收剂的吸附机制和动力学.
主要方法:
- 四种基托衍生物的制备和表征:N,O-carboxymethyl基托 (N,O-CM/Cs),基托与甲接种 (Cs/GA),基托与GA/epichlorohydrin交叉连接 (Cs/GA/ECH),基托与甲/甲基乙交叉连接 (Cs/GA/MBA).
- 使用模拟的MB染料溶液进行了吸附实验,以确定吸附能力,并优化膨胀条件 (pH,温度,时间).
- 吸附动力学和异热量分别使用伪二阶模型和朗慕尔模型进行了分析. 原子力显微镜 (AFM) 用于可视化染料吸附.
主要成果:
- 酸盐衍生物表现出优异的机械性能,可在五个周期内重复使用,以及MB染料的显著吸附能力.
- 吸附能力是按照以下顺序进行的:N,O-CM/Cs (95.1 mg/g) < Cs/GA (120.1 mg/g) < Cs/GA/ECH (220.1 mg/g) < Cs/GA/MBA (270.0 mg/g). 吸附能力是按照以下顺序进行的:N,O-CM/Cs (95.1 mg/g) < Cs/GA (120.1 mg/g) < Cs/GA/ECH (220.1 mg/g) < Cs/GA/MBA (270.0 mg/g).
- 在pH值为9,温度为55°C时,并在24小时后获得了剂的最大胀. 吸附遵循伪二阶动力学和兰格穆尔模型.
结论:
- 改性奇托衍生物,特别是Cs/GA/MBA,是高效且可重复使用的吸附剂,用于从废水中去除危险的甲蓝染料.
- 膨胀行为和吸附动力学提供了对染料去除最佳条件和机制的见解.
- 这项研究突出了针对环境修复应用量身定制的酸盐基材料的潜力.
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