真空沉积的矿具有可控制的晶体方向
Jin Yan1,2, Lena Sophie Stickel1,3, Lennart van den Hengel2
1PVMD Group, Delft University of Technology, Mekelweg 4, 2628 CD Delft, The Netherlands.
The journal of physical chemistry letters
|September 25, 2023
概括
通过热蒸发控制矿 (PVK) 晶体的方向至关重要. 中间回火温度可以调整PVK (100) 方向,增强光发光和表面均性,以更好地提取电荷.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 光电学是指光电子产品.
背景情况:
- 矿 (PVK) 的方向是光电子特性的关键,通常通过湿处理控制.
- 在热蒸发的PVK薄膜中控制晶体方向仍未得到充分研究.
- 晶体定向对电荷载体的移动性,寿命和蒸发PVK中的陷密度的影响尚不清楚.
研究的目的:
- 为了研究中间回火温度对热蒸发的矿膜的晶体方向的影响.
- 分析不同的晶体方向如何影响这些膜的光电子特性.
- 为了确定控制方向是否可以提高PVK膜的性能,用于设备应用.
主要方法:
- Cs0.15FA0.85PbI2.85Br0.15的连续热蒸发,其间的火温度不同 (Tinter).
- 用X射线衍射 (XRD) 和2D-XRD来描述晶体的方向.
- 光导率,光发光率 (PL) 产量和寿命测量.
- 凯尔文探针力显微镜 (KPFM) 用于接触电位差异 (CPD) 映射.
主要成果:
- 没有中间回火,主要产生 (110) 方向.
- Tinter = 100 °C导致几乎同位素的方向.
- 在Tinter>>130°C下,产生了高度定向 (100) 的PVK片.
- 大量电子特性 (光导性) 是独立于方向的.
- 表面特性,包括PL产量,寿命和表面潜力的均性 (通过KPFM),在 (100) 方向下显著改善.
结论:
- 中间是一种有效的方法来控制热蒸发PVK中的晶体方向.
- 高度定向 (100) PVK 薄膜表现出优异的光发光和表面均性.
- 控制的 (100) 方向有利于提高矿设备中的电荷提取效率.
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