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相关概念视频

Ionic Bonds00:42

Ionic Bonds

118.6K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
118.6K
Electrolysis03:00

Electrolysis

26.6K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.6K
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

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Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
63.2K
Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.6K
DC Battery01:21

DC Battery

822
A conductor needs to be a component of a path that creates a closed loop or full circuit to have a continuous current flowing through it. A current starts to flow if an electric field is created inside an isolated conductor that is not part of a full circuit. The conductor quickly develops a net positive charge at one end and a net negative charge at the other. These charges generate an electric field opposite the direction of the applied electric field, which reduces the current. Eventually,...
822
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

14.7K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.7K

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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在水性电池中的电解质间相.

Yiming Sui1, Xiulei Ji1

  • 1Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003, USA.

Angewandte Chemie (International ed. in English)
|September 25, 2023
PubMed
概括

由于水的电化学稳定性有限,水性电解质面临挑战. 本综述探讨了使用添加剂和辅溶剂在水性电池中创建保护界面 (SEI和CEI) 的策略.

科学领域:

  • 电化学 电化学 电化学
  • 材料科学 材料科学 材料科学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 水性电解质受到水的狭窄电化学稳定性窗口的限制.
  • 与非水性系统不同,水电解产品不会在电极上形成保护性被动化层.
  • 这就需要在水性电池系统中设计稳定接口的策略.

研究的目的:

  • 审查水性电池中电解质相间形成的基本原理.
  • 要突出最近在水性电解质中创建固体电解质介面 (SEI) 和阴极电解质介面 (CEI) 的进展.
  • 为了应对水有限的电化学稳定性所带来的挑战.

主要方法:

  • 关于基本电化学原理的文献综述.
  • 对水性电解质的添加剂和辅溶剂的最新研究进行分析.
  • 在水性电池系统中讨论SEI和CEI形成机制.

主要成果:

  • 水性电解质需要特定的添加剂或辅溶剂来形成保护性SEI和CEI层.
  • 工程界面对于克服水的电化学稳定性的局限性至关重要.
  • 最近的进展侧重于量身定制的组件设计,以提高界面稳定性.
关键词:
一个水性电池.电解质相间阶段的电解质电解质是一种电解质.气体进化 气体进化

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结论:

  • 水性电池的成功开发依赖于稳定的SEI和CEI层的有效生成.
  • 了解和控制相间形成是释放水性电解质潜力的关键.
  • 对新型添加剂和辅溶剂的进一步研究将推动水性能量存储的进步.